New mineral activity–composition relations for thermodynamic calculations in metapelitic systems     

R. W. White  R. Powell  T. J. B. Holland  T. E. Johnson  E. C. R. Green 《Journal of Metamorphic Geology》2014,32(3):261-286

New activity–composition (a–x) relations for minerals commonly occurring in metapelites are presented for use with the internally consistent thermodynamic dataset of Holland & Powell ( 2011 , Journal of Metamorphic Geology, 29 , 333–383). The a–x relations include a broader consideration of Fe₂O₃ in minerals, changes to the formalism of several phases and order–disorder in all ferromagnesian minerals where Fe–Mg mixing occurs on multiple sites. The a–x relations for chlorite, biotite, garnet, chloritoid, staurolite, cordierite, orthopyroxene, muscovite, paragonite and margarite have been substantially reparameterized using the approach outlined in the companion paper in this issue. For the first time, the entire set of a–x relations for the common ferromagnesian minerals in metapelitic rocks is parameterized simultaneously, with attention paid to ensuring that they can be used together to calculate phase diagrams of geologically appropriate topology. The a–x relations developed are for use in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O₂ (NCKFMASHTO) system for both subsolidus and suprasolidus conditions. Petrogenetic grids in KFMASH and KFMASHTO are similar in topology to those produced with earlier end‐member datasets and a–x relations, but with some notable differences. In particular, in subsolidus equilibria, the FeO/(FeO + MgO) of garnet is now greater than in coexisting staurolite, bringing a number of key staurolite‐bearing equilibria into better agreement with inferences from field and petrographic observations. Furthermore, the addition of Fe³⁺ and Ti to a number of silicate phases allows more plausible equilibria to be calculated in relevant systems. Pseudosections calculated with the new a–x relations are also topologically similar to equivalent diagrams using earlier a–x relations, although with many low variance fields shifting in P–T space to somewhat lower pressure conditions.  相似文献   

Provenance of sediment in the Labrador Current: a record of hinterland glaciation over the past 125 ka          下载免费PDF全文

LONGJIANG MAO  DAVID J. W. PIPER  FRANCKY SAINT‐ANGE  JOHN T. ANDREWS  MARKUS KIENAST 《第四纪科学杂志》2014,29(7):650-660

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Late Quaternary (Marine Isotope Stage 3 to Recent) sedimentary evolution of the Basque shelf (southern Bay of Biscay)     

Blanca Martínez‐García  Arantxa Bodego  Jone Mendicoa  Ana Pascual  Julio Rodríguez‐Lázaro 《Boreas: An International Journal of Quaternary Research》2014,43(4):973-988

Late Quaternary (MIS 3 to Recent) oceanographic evolution of the Basque shelf has been analysed for the first time based on the sedimentological analysis of three cores obtained from the middle and outer shelves. The cores are located in two interfluves separated by the San Sebastian canyon. The variability of the percentage of the planktonic foraminifera species Neogloboquadrina pachyderma sin. and of δ¹⁸O_bull allowed us to identify the influence of colder and warmer waters in the Basque shelf during the late Quaternary. From ～56 cal. ka BP to the end of the Last Glacial Maximum (19 cal. ka BP) the sedimentary record shows a decreasing trend in the mean grain size that correlates with the eustatic sea‐level fall. The last Deglaciation (19–11.5 cal. ka BP) is characterized by a sea‐level rise that produced an important hiatus in the western outer shelf. During the Holocene, the middle and outer shelves present different behaviours. From 11.5 to 6.7 cal. ka BP, in the outer shelf the sea‐level rise that started during the Deglaciation produced a hiatus, whereas in the middle shelf the sedimentary succession records the presence of warm to temperate waters. Between 6.7–4.9 cal. ka BP, the entrance of cold surface water‐masses that only affected the middle shelf has been identified, and temperate to warm waters occurred in the outer shelf. The cold surface water‐masses retreated during 4.9–4.3 cal. ka BP in the middle shelf. Finally, from 4.3 cal. ka BP to Recent, the middle shelf registers a hiatus due to sea‐level stabilization after a generalized transgression, synchronous to a decrease in the energy of the water‐masses in the outer shelf. In conclusion, the environmental changes detected in the Basque shelf are attributed to both regional and eustatic sea‐level changes.  相似文献   

Slab–mantle flow interaction: influence on subduction dynamics and duration     

Juan Rodríguez‐González  Ana M. Negredo  Eugenio Carminati 《地学学报》2014,26(4):265-272

We investigate the influence of mantle flow relative to the lithosphere on subduction dynamics. We use 2D thermo‐mechanical models assuming incompressible non‐Newtonian fluid rheology. Different mantle flow velocities consistent with absolute plate motion models are tested, as well as both directions of flow, either sustaining or opposing slab dip. The effects of different inflow/outflow velocity profiles, slab strengths and upper–lower mantle viscosity contrasts are also evaluated. Slab dip deviations between models with opposite mantle flow directions range from 37° for relatively strong slabs (η_max = 10²⁵ Pa s) to 50° for weaker slabs (η_max = 10²⁴ Pa s), accounting for a significant amount of natural slab dip variability. For imposed mantle flow supporting the slab, the initial stage of slab steepening is followed by a stage of continuous slab dip decrease. This slab shallowing eventually leads to mantle wedge closure, subduction cessation and slab break‐off, possibly driving subduction flips.  相似文献   

Using hydrogeochemical signatures of stream water to assess pathways for rainfall events: towards a predictive model          下载免费PDF全文

J. A. Figueiredo  E. A. Menor  M. T. Taboada‐Castro  M. M. Taboada‐Castro  M. L. Rodríguez‐Blanco  E. S. Braga 《水文研究》2014,28(4):2302-2311

Thanks to its simple division into agricultural and forestry land use, the Corbeira catchment (Galicia, Spain) is used as a case study to build a predictive model using hydrogeochemical signatures. Stream data acquired under recessional flow conditions over a one year period were obtained from a sampling station near the downstream end of the catchment, and using principal component analysis, it is shown that some of the analytical parameters are covariant, and some are negatively correlated. These findings support inferences about the pathways of rainfall in the catchment. Specific signatures may be associated with the dominant hydrological source, either surface runoff or subsurface waters: additionally, the dominant land use in that part of the catchment, where the flow originated, can also be predicted. The dominant runoff shows a strong covariance between suspended solids (SS) and particulate phosphorus (PP), with a clear negative correlation with pH. Dissolved organic carbon (DOC) data are associated with this covariant set when these compounds are available in the soils in question. Dissolved phosphorus, total organic nitrogen and dissolved nitrates are also associated with the same covariant set when the runoff flows through areas of extensive agricultural use. The SS ? PP covariance is less significant at lower flows. Typical base flow regimes show a significant covariance between salinity and pH, with a marked negative correlation with SS ? PP set, confirming the dominance of subsurface waters in the baseflow, as expected. Seasonally divergent DOC ? SS behaviour proves to be a useful tracer for rainfall regimes. The DOC trend shows a sinusoidal annual variation in amplitude, determined by the rainfall regime. As a result, flow from the catchment is dominated by surface water whenever there is synchronicity between the peaks of DOC and SS. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Study of the Galactic Rotation Based on Masers and Radio Stars with VLBI Measurements of Their Parallaxes     

Bobylev  V. V.  Krisanova  O. I.  Bajkova  A. T. 《Astronomy Letters》2020,46(7):439-448

Astronomy Letters - Based on published data, we have produced a sample of 256 radio sources whose trigonometric parallaxes and proper motions were measured by VLBI. This sample contains Galactic...  相似文献   

Understanding the Past and Present and Predicting the Future: Farmers’ Use of Multiple Nutrient Best Management Practices in the Upper Midwest     

Riva C. H. Denny  Sandra T. Marquart-Pyatt  Matthew Houser 《社会与自然资源》2019,32(7):807-826

Understanding what drives farmers’ voluntary adoption of nutrient and soil best management practices has important consequences for many environmental outcomes including water quality. We build on research revealing the need for simultaneous use of multiple nitrogen best management practices to achieve water quality improvement goals. Using social, economic and attitudinal variables we predict the use of multiple nitrogen best management practices at three time points: current use (2013), past use (before 2013), and likelihood of use on their largest field in the next three years. Our empirical analysis uses structural equation modeling with latent variables and 2014 farmer survey data from three Midwestern US states. Most farmers in our sample used at least one of the six best management practices. Our results reveal that farmers’ attitudes, use of information sources, and conservation program participation affect the number of nitrogen best management practices concurrently in use at multiple time points.  相似文献   

Portlandia-dominated Communities in the Arctic: Taxonomic Composition and Structure along the Geographical Gradient     

Mokievsky  V. O.  Udalov  A. A.  Chava  A. I.  Simakova  U. V.  Kokarev  V. N.  Neretina  T. V. 《Doklady Earth Sciences》2020,493(2):645-648

Doklady Earth Sciences - The species composition and structure of bottom communities with a predominance of bivalve mollusks of the Portlandia genus, which are widespread on the shelf of the...  相似文献   

The Dudica Epithermal Cu–Au Deposit (Republic of North Macedonia)     

Tasev  G.  Serafimovski  D.  Volkov  A. V.  Boev  B.  Djordjevic  T.  Kolitsch  U.  Serafimovski  T. 《Geology of Ore Deposits》2020,62(5):419-431

Geology of Ore Deposits - The Dudica deposit is located in the southern part of the Republic of North Macedonia (RNM), not far from the border with Greece in the Kozuf–Aridean volcanic...  相似文献   

Crystal Structure of Yushkinite [(Mg0.60Al0.30V0.10)Σ1.0(OH)2][V0.875S2]: An Example of a Commensurate Combination of Brucite and Sulfide Layers     

Soboleva  S. V.  Evstigneeva  T. E.  Boeva  N. M.  Bortnikov  N. S. 《Doklady Earth Sciences》2020,491(2):210-213

Doklady Earth Sciences - A structural model of the rare mineral yushkinite [(Mg0.60Al0.30V0.10)Σ1.0(OH)2] [V0.875S2] is studied using the data of electron microdiffraction and the X-ray powder...  相似文献